Daphenylline, a new alkaloid with an unusual skeleton, from Daphniphyllum longeracemosum.
Journal: 2009/June - Organic Letters
ISSN: 1523-7052
Abstract:
A new alkaloid, daphenylline (1), with an unprecedented rearranged 22-nor-calyciphylline skeleton, was isolated from the fruits of Daphniphyllum longeracemosum. Its structure and stereochemistry were elucidated on the basis of spectroscopic and computational approaches. A plausible biosynthetic pathway of 1 was also proposed.
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